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VALUE REGULATED LEAD ACID BATTERY
Material Safety Data Sheet
Revised:
May 2000
Trade Name: Gel; Absorbed Electrolyte, Sealed
Valve Regulated Non Spillable Battery
Classification: Battery wet, filled with acid, electric storage UN2794
Emergency Telephone Number: CHEMTREC 1-800-424-9300
In Washington, D.C. or outside Continental U.S., call 1-202-483-7616
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SECTION II
HAZARDOUS INGREDIENTS/IDENTITY INFORMATION |
Hazardous Components
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Specific Chemical Identity
(Common Name(s)) |
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OSHA PEL |
ACGIH TLV |
% RANGE |
AVERAGE |
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Lead,
CAS #7439921 |
0.05 mg/m³ |
0.05 mg/m³ |
60-75% |
67% |
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Sulfuric Acid,
CAS#7664939 |
1.00 mg/m³ |
1.00 mg/m³ |
5-15% |
10% |
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Antimony,
CAS #7440360 |
0.50 mg/m³ |
0.50 mg/m³ |
0-0.1% |
<0.1% |
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Arsenic,
CAS #7440382 |
0.01 mg/m³ |
0.01 mg/m³ |
0.01% |
<0.1% |
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Polypropylene,
CAS #9003070 |
------------ |
------------ |
2-10% |
4% |
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Calcium,
CAS #7440702 |
1.0 mg/m³ |
1.0 mg/m³ |
0-0.1% |
<0.1% |
Tin,
CAS #7440702 |
2.0 mg/m³ |
2.0 mg/m³ |
0-0.1% |
<0.1% |
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SECTION III
PHYSICAL/CHEMICAL CHARACTERISTICS |
Electrolyte (Sulfuric Acid):
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Appearance and Odor:
clean, odorless, colorless liquid |
Solubility in Water: 100% |
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Boiling Point: approximately 235-240ºF |
Specific Gravity (H²O=1):
1.270 – 1.330 |
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Evaporation Rate (Butyl
Acetate=1):
less than 1.0 |
Vapor Density (AIR=1):
Greater than 1 |
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Melting Point: N/A |
Vapor Pressure (mm Hg): 10 |
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SECTION IV
FIRE AND EXPLOSION HAZARD DATA |
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Flash Point (Method Used): Non-flammable |
Flammable Limits: *Hydrogen gas |
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Extinguishing Media: Class ABC
extinguisher |
LEL: 4% |
UEL: 74% |
NOTE: CO² may be used, but not directly on the cell. The thermal shock may cause cracking of the battery case and/or cases.
*Hydrogen gas may be generated during battery changing.
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SECTION V
REACTIVITY DATA |
Stability: Stable
Condition to Avoid: Prolonged overcharging, sources of ignition.
Incompatibility (Material to Avoid): Sulfuric Acid: Contact with combustibles and organic material may cause fire and explosion. Also reacts violently with strong reducing agents, metals, strong oxidizers and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas.
Hazardous Decomposition of By-Products: Sulfuric Acid: Excessive overcharging or fire may create sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide and hydrogen.
Lead Compounds: Contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas.
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SECTION VI
HEALTH HAZARD DATA |
Route(s) of Entry: Not applicable under normal use. (Inhalation, skin contact and ingestion)
Carcinogenicity:
Sulfuric Acid: The International Agency for Research on Cancer (IARC) has classified “strong inorganic acid mist containing sulfuric acid” as a Category 1 carcinogen, a substance that is carcinogenic to humans. This classification does not apply to liquid forms of sulfuric acid contained within a battery. Inorganic acid mist (sulfuric acid mist) is not generated under normal use of this product. Misuse of the product such as overcharging, may result in the generation of sulfuric acid mist.
Lead Compounds: Lead is listed as a 2B carcinogen, likely in animals at extreme doses. Proof of carcinogenicity in humans is lacking at present.
Arsenic: Listed by National Toxicology Program (NTP), IARC, OSHA and NIOSH as a carcinogen only after prolonged exposure at high levels.
Signs and Symptoms of Exposure: Avoid contact, with absorbed electrolyte (sulfuric acid) may cause irritation of eyes, nose and throat. Contact with eyes and skin causes irritation and skin burns. Absorbed electrolyte is corrosive.
Medical Conditions Generally Aggravated by Exposure: Pregnant women and
children must be protected from lead exposure.
Health Hazards (Acute and Chronic): Do not
open battery, avoid contact with internal components. Internal components
include lead and absorbed electrolyte. Electrolyte is corrosive and
contact may cause skin irritation and chemical burns.
Emergency and First Aid Procedures: (Sulfuric Acid)
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Flush contacted area with large amounts of water for at least 15 minutes. Remove contaminated clothing and obtain medical attention if necessary. Eye wash and/or emergency shower should be readily available.
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If swallowed, give large volumes of water DO NOT induce vomiting, obtain medical treatment.
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SECTION VII
PRECAUTIONS FOR SAFE HANDLING AND USE |
Steps to be Taken in Case Material is Released or
Spilled: Electrolyte material is corrosive. Contains sulfuric acid. Neutralize any spilled material. Reference 1996 North American Emergency Response Guidebook, #154
Waste Disposal Method: Lead acid batteries are completely recyclable. For information on returning batteries for recycling, contact your Dynacell representative. Dispose of any collected material in accordance with local, state or applicable federal regulations.
Other Precautions: If battery case is broken, avoid direct contact with internal components. Keep away from ignition sources during charging.
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SECTION VIII
CONTROL MEASURES |
Respiratory Protection (Specific Type): N/A
Ventilation: Must be provided when charging in an enclosed area.
Protective Gloves: Recommended
Eye Protection: Recommended
Other Protective Clothing or Equipment: N/A
Work Hygienic Practices: Good personal hygiene and work practices are recommended.
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SECTION IX
OTHER REGULATORY INFORMATION |
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NFPA Hazard Rating |
Sulfuric Acid |
Lead |
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Health (blue) |
3 |
3 |
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Flammability (red) |
0 |
0 |
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Reactivity (yellow) |
2 |
0 |
Note: Sulfuric acid is water-reactive if concentrated.
U.S.DOT: The non-spillable lead acid battery complies with the provisions listed in 49CFR173.159(d) therefore, must not be marked with an identification number, such as UN2800, or a hazard label, such as corrosive. Also, having passed IATA/ICAAO special provision A67, these batteries are not subject to the air dangerous goods regulations.
RCRA: Spent lead-acid batteries are not regulated as hazardous waste when recycled. Spilled sulfuric acid is a characteristic hazardous waste. EPA hazardous waste number D002 (corrosivity)
CERCLA (Superfund) and EPCRA (Emergency Planning and Community Right to Know Act)
a) Reportable Quantity (RQ) for spilled 100% sulfuric acid is 1,000 lbs.
b) Sulfuric acid is a listed “Extremely Hazardous Substance” under EPCRA with a Threshold Planning Quantity (TPQ) of 1,000 lbs.
c) EPCRA Section 312 Tier II reporting required for batteries if sulfuric acid is present in quantities of 500 lbs. or more and/or lead is present in quantities of 10,000 lbs. or more
California Prop 65: This product contains chemicals known to the State of California to cause cancer, birth defects and other reproductive harm.
For additional information concerning East Penn Manufacturing Co., Inc. products or questions concerning the content of this MSDS, please contact your DYNACELL representative.
This information is accurate to the best of our knowledge or obtained from sources believed by us to be accurate. Before using any product, read all warnings and directions on the label.
The Federal I.D. number for East Penn's recycling facility if #23-1315454. This
recycling facility recycles used lead-acid batteries under license number EPA PAD 002330165.
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